environmental impact of the wastewater treatment process. The energy demand was identified as the main environmental hotspot in the LCA analysis. The analysis revealed that the energy source for electricity generation had a significant influence on the overall sustainability of this system. Additionally, the wood itself, a naturally abundant and eco-friendly material, presented zero environmental hazard to the environment during the filtration process. The experimental and environmental impact results indicate that Gb-wood can be employed as a natural and eco-friendly adsorbent material for the removal of waste from aqueous solutions. Copyright © 2020 American Chemical Society.In this work, a mild and sustainable catalytic aerobic epoxidation of alkenes catalyzed by cobalt porphyrin was performed in the presence of sunflower seeds oil. Under ambient conditions, the conversion rate of trans-stilbene reached 99%, and selectivity toward epoxide formation was 88%. The kinetic studies showed that the aerobic epoxidation followed the Michaelis-Menten kinetics. Mass spectroscopy and in situ electron spin resonance indicated that linoleic acid was converted to fatty aldehydes via hydroperoxide intermediates. A plausible mechanism of epoxidation of alkenes was accordingly proposed. Copyright © 2020 American Chemical Society.The solid-liquid equilibrium data of the aqueous NaOH-Na2CO3-Na2SO4-H2O, NaOH-Na2CO3-NaCl-H2O, and NaOH-Na2SO4-NaCl-H2O quaternary systems at 363.15 K were measured. The equilibrium solid phases and solubilities of salts in the three systems and its subsystems were determined. The densities of the saturated solutions were also determined. The experimental data are used to plot the solubility diagrams and water content diagrams of the systems. It was found that the NaOH-Na2CO3-Na2SO4-H2O system contains the solid solution of γ-salt (mNa2SO4·nNa2CO3) and the other two systems Na2CO3-NaOH-NaCl-H2O and NaOH-Na2SO4-NaCl-H2O have the complex salts S1 (Na2SO4·NaOH) and S3 (Na2SO4·NaCl·NaOH). On the basis of Xu’s activity coefficient model, a model was constructed for the correlation of solid-liquid equilibrium in electrolyte solutions to calculate the solubilities of salts in these systems at 363.15 K. The calculated solubilities are in agreement with the experimental values. Copyright © 2020 American Chemical Society.A copolymer comprising of pyrrole and 1,4-butanediol diglycidyl ether (PBDGE) was designed and synthesized as a leveler to improve the throwing power for printed circuit board (PCB) through-hole electroplating. The results of linear sweep voltammetry (LSV), galvanostatic measurements (GMs), and cyclic voltammetry (CV) reveal the strong coordination effect of PBDGE with other additives and confirm the advantageous performance of PBDGE to effectively assist the electroplating of through-hole. An increment of 35.5% in the throwing power was achieved under the addition of PBDGE in through-hole plating. Additionally, the reaction mechanism was studied by quantum chemical calculations and molecular dynamics (MD) simulations, indicating that the pyrrole rings of the PBDGE molecule are adsorbed on the copper surface as the adsorption sites to balance the copper plating regardless of the through-hole position differences. Copyright © 2020 American Chemical Society.Microwave-ultrasound-assisted facile synthesis of a dumbbell- and flower-shaped potato starch phosphate (PSP) polymer, hereafter PSP, was carried out by cross-linking the hydroxyl groups of native potato starch (NPS) using phosphoryl chloride as a cross-linking agent. Structural and morphological analysis manifested the successful formation of the dumbbell- and flower-shaped PSP biosorbent with enhanced specific surface area and thermal stability. Viscoelastic behavior of NPS and PSP suggested increased rigidity in PSP, which helped the material to store more deformation energy in an elastic manner. The synthesized PSP biosorbent material was successfully tested for efficient and quick uptake of Zn(II), Pb(II), Cd(II), and Hg(II) ions from aqueous medium under competitive and noncompetitive batch conditions with q m values of 130.54, 106.25, 91.84, and 51.38 mg g-1, respectively. The adsorption selectivity was in consonance with Pearson’s hard and soft acids and bases (HSAB) theory in addition to their order of hydrated radius. Adsorption of Zn(II), Pb(II), Cd(II), and Hg(II) followed a second-order kinetics and the adsorption data fitted well with the Langmuir isotherm model. Quantum computations using density functional theory (DFT) further supported the experimental adsorption selectivity, Zn(II) > Pb(II) > Cd(II) > Hg(II), in terms of metal-oxygen binding energy measurements. T-DM1 manufacturer What was more intriguing about PSP was its reusability over multiple adsorption cycles by treating the metal(II)-complexed PSP with 0.1 M HCl without any appreciable loss of its adsorption capacity. Copyright © 2020 American Chemical Society.The CO2 capture from back-up power plants by making use of calcium looping systems combined with large piles of Ca-solids has been studied in this work. A flexible CO2 capture system based on a concept described in a previous work has been integrated into an existing power plant by including a small oxy-fired calciner (that represents just 8% of the total thermal capacity) to steadily regenerate the sorbent and a carbonator reactor following the back-up power plant operation periods to capture 90% of the CO2 as CaCO3 and two large piles of rich CaO and CaCO3 solids stored at modest temperatures. When the back-up plant enters into operation, the calcined solids are brought into contact with the flue gases in the carbonator reactor; meanwhile, the oxy-calciner operates continuously at a steady state. In order to improve the flexibility of the CO2 capture system and to minimize the increase of CO2 capture costs associated with the additional new equipment used only during the brief back-up periods, we propose using the steam cycle of the existing power plant to recover a large fraction of the heat available from the streams leaving the carbonator. This makes it possible to maintain the electrical power output but reducing the thermal input to the power plant by 12% and thus the size of the associated CO2 capture equipment. To generate the auxiliary power required for the oxy-calciner block, a small steam cycle is designed by integrating the waste heat from the streams leaving this reactor. By solving the mass and heat balances and proposing a feasible thermal integration scheme by using Aspen Hysys, it has been calculated that the CO2 emitted by long-amortized power plants operated as back-up can be captured with a net efficiency of 28%. Copyright © 2020 American Chemical Society.